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Rate parameters for
nine types of reactions, which are supposed to be
important in the low temperature chemistry of alkane
oxidation, were estimated based on the knowledge
of thermochemistry described in literature available.
The estimation includes the low temperature degenerate
branching reaction O2QOOH→ R'OOH+OH,
isomerization RO2→ QOOH, The reactions
following or preceding them, and others. The results
of computer simulation using a model of n-butane
autoignition chemistry, which was constructed with
the reactions estimated in this article , is also
presented.
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