High dielectric insulators have been widely studied
for their application to thin film capacitors.
Among these insulators, tantalum oxide ( Ta2O5)
is an attractive material for VLSI and optoelectronic
devices, because of its high breakdown voltage
and dielectric constant.
Electrical properties of Ta2O5
and Ta2O5-based composite
films prepared by magnetron sputtering have been
investigated in view of their O/Ta ratios, impurities,
and micro structures. As additive oxides, Y2O3and
WO3 were found to be effective materials
for improving insulating properties without decreasing
their dielectric constant. Furthermore, measurements
of the temperature dependence of the leakage current
revealed that the conduction mechanism at RT changed
from the Poole-Frenkel type to the Fowler-Nordheim
tunneling type by adding Y2O3
or WO3 into Ta2O5.
Based on the detailed analysis of the results,
it is concluded that the addition of Y2O3
and WO3 into the Ta2O5
film is effective in the reduction of the defect
density without high-temperature annealing and
alteration of the electrical conduction mechanism
of the films.
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