Vol.30 No.4(1995.12)
Research Report

Preparation of High dielectric Ta2O5-based Composite Films

Hisayoshi Fujikawa, Koji Noda, Yasunori Taga


High dielectric insulators have been widely studied for their application to thin film capacitors. Among these insulators, tantalum oxide ( Ta2O5) is an attractive material for VLSI and optoelectronic devices, because of its high breakdown voltage and dielectric constant.

Electrical properties of Ta2O5 and Ta2O5-based composite films prepared by magnetron sputtering have been investigated in view of their O/Ta ratios, impurities, and micro structures. As additive oxides, Y2O3and WO3 were found to be effective materials for improving insulating properties without decreasing their dielectric constant. Furthermore, measurements of the temperature dependence of the leakage current revealed that the conduction mechanism at RT changed from the Poole-Frenkel type to the Fowler-Nordheim tunneling type by adding Y2O3 or WO3 into Ta2O5. Based on the detailed analysis of the results, it is concluded that the addition of Y2O3 and WO3 into the Ta2O5 film is effective in the reduction of the defect density without high-temperature annealing and alteration of the electrical conduction mechanism of the films.

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