Vol.32 No.2(1997.6)
Research Report

Effect of Ca, Mg on Hydrogen Absorption of Molten Al-Si Alloy

Hiroshi Kawahara, Yoji Awano


For reducing the inferior castings of aluminum alloys caused by porosity it is necessary to clarify, the shrinkage morphology of poured melt and the factors affecting the change in shrinkage morphology. In this study, the change in the amount of porosity was investigated for JIS AC2B secondary alloy ingots from the viewpoint of hydrogen absorption by using a conical mold developed for evaluating the shrinkage morphology. The amount of porosity changes, mainly depending on the holding time and temperature of the molten metal as well as the humidity in the holding atmosphere. The change in the amount of porosity differs according to raw ingots, because the quantity of the hydrogen absorbed in the molten metal is different. The hydrogen absorption is closely related with the oxidation of the molten metal. Particularly, in the case of the ingot containing both Mg and Ca, remarkable hydrogen absorption occurred even during a short holding time, and the oxide formed on the melt surface was sunk. It is considered that the oxide is sunk because Ca improves the wettability between the oxide and the molten metal. This suggests that the oxidation of the melt is promoted, causing remarkable hydrogen absorption. It is found effective for minimizing the change in the amount of porosity to retard the melt oxidation by Be addition and to remove Ca by SF6 gas bubbling.
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