Nitrogen-doped 6H-SiC single crystals were grown
by the modified Lely method (the sublimation method).
The crystallinity and electrical properties of
the grown crystals were investigated through optical
absorption measurements, Hall measurements (van
der Pauw method) and etch pit measurements (the
molten alkaline etching method). Nitrogen gas
was introduced into the furnace with a partial
pressure of 0.05-0.8 Torr during the crystal growth.
The nitrogen concentration in the crystals increased
with the nitrogen partial pressure. The etch pit
density (EPD) increased as the nitrogen concentration
increased. The increase in the number of etch
pits was ascribed to the increase in rows of edge
dislocations (subgrain boundaries). It is suggested
that the nitrogen incorporated in the crystal
might trigger the generation of subgrain boundaries.
It should be noted, however, that the amount of
doped nitrogen did not affect the micropipe densities
(MPD: ~1cm-2). A 6H-SiC wafer (12 mm
in diameter) with resistivity as low as 0.03Wcm
was obtained with relatively low defect densities
(MPD: 1 cm-2, EPD: 4.5x104
cm-2).