For measuring the oil consumption in an engine,
the Non Dispersive Infrared Red Analyzer method
(NDIR) and the Flame Photometric Detector method
(FPD) are used in general. However, these methods
have some problems of the low detection-limit
and the inhibition caused by NOx in the exhaust
gas. We integrated a new detection method with
enzyme, chemiluminescence and the flow injection
analysis (FIA), and developed a continuous high-sensitivity
exhaust SO2 analyzer which detects
SO2 at a ppb level and is not inhibited
by exhaust gas. First, SO2 in the exhaust
gas was trapped in water by a gas/solution exchanging
membrane. Second, the immobilized sulfite oxidase
used for a specific catalyst produces H2O2
by oxidation of SO32-, and
finally determined by peroxyoxalate chemiluminescence.
This method made it possible to measure the
change of an exhaust SO2 at LA-4 mode
in real-time with no inhibition in a gasoline
engine. Also we measured the oil consumption in
a diesel engine. As a result, our method proved
be useful for measuring the oil consumption. This
new method is expected to apply not only to the
support for engine development but also to the
measurement of environmental factors including
specific gas composition.
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