Vol.36 No.3(2001.9)
Special Issue / Research Report
Novel Microstructure Inorganic Materials Developed by New Synthetic Technologies

Highly Textured Piezoelectric Ceramics by RTGG Method
Toshihiko Tani

We have proposed the reactive templated grain growth (RTGG) method, in which highly textured ceramics are fabricated by the reaction between aligned template particles and supplementary ingredient materials. This process produces successive grain growth during heat treatment. A regular perovskite-type structured Bi0.5(Na,K)0.5TiO3 (BNKT) bulk ceramic with a preferred <100> orientation was prepared using Bi4Ti3O12 (BiT) platelets as a reactive template. The textured BNKT ceramics exhibited higher piezoelectric properties and a lower dielectric loss than randomly oriented ceramics with the same composition. The proposed method has been extended to bismuth layer-structured ferroelectrics and oxide thermoelectrics.