We have proposed the reactive templated grain
growth (RTGG) method, in which highly textured
ceramics are fabricated by the reaction between
aligned template particles and supplementary ingredient
materials. This process produces successive grain
growth during heat treatment. A regular perovskite-type
structured Bi0.5(Na,K)0.5TiO3
(BNKT) bulk ceramic with a preferred <100>
orientation was prepared using Bi4Ti3O12
(BiT) platelets as a reactive template. The textured
BNKT ceramics exhibited higher piezoelectric properties
and a lower dielectric loss than randomly oriented
ceramics with the same composition. The proposed
method has been extended to bismuth layer-structured
ferroelectrics and oxide thermoelectrics.