Technical Journal R&D Review
Abstract : Vol.37No.3(2002.9)
Special Issure : Challenges in Realizing Clean High-Performance Diesel Engines
Review
 
P.1 Research and Development Trends in Combustion and Aftertreatment Systems for Next-Generation HSDI Diesel Engines
   

Kiyomi Nakakita

 

 

Recently, the performance and exhaust emissions of high-speed direct injection (HSDI) diesel engines for passenger cars have been rapidly improved. In these engines, the power and torque densities have reached 50-60 kW/l and 160-170 Nm/l, respectively. In addition, the noise, vibration and harshness (NVH) and exhaust emissions have been decreasing toward a level that is comparable to that of gasoline engines. Furthermore, the maximum brake thermal efficiency has reached 42-43% and both city and highway fuel economy is excellent. Therefore, the percentage of diesel passenger cars in Europe has been increasing remarkably and is forecasted to reach 48% in 2007.

The developments of common-rail (CR) injection systems, high-efficiency aftertreatment devices such as the diesel particulate filter (DPF) and catalysts, and advanced electronic control systems are listed as major technical backgrounds of the progress in HSDI diesel engines. In the present review, recent trends in research and development of the above-listed component technologies, primarily regarding combustion and aftertreatment systems, are outlined. Finally, critical technical areas that must be addressed in order to realize an ultra-clean and high-performance diesel engine are presented.

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Research Report
 
P.9 Achieving Lower Exhaust Emissions and Better Performance in an HSDI Diesel Engine with Multiple Injection
   
Yoshihiro Hotta, Minaji Inayoshi,
Kiyomi Nakakita

 

 

The effects of multiple injection on exhaust emissions and performance in a small HSDI (High Speed Direct Injection) Diesel engine are investigated. It is possible to increase the maximum torque, which is limited by the exhaust smoke number, while decreasing the combustion noise under low speed, full load conditions by advancing the timing of the pilot injection. Dividing this early-timed pilot injection into a series of smaller injections serves to further decrease the noise while suppressing the increase of HC emission and fuel consumption. These effects result from the enhanced heat release rate of the pilot injection fuel, which is due to the reduced amount of adhered fuel on the cylinder wall. At light loads, the amount of pilot injection fuel must be reduced, and the injection must be timed just prior to the main injection in order to suppress a possible increase in smoke and HC. After-injection, a small amount of fuel injected immediately after the end of the main injection, reduces smoke, HC and fuel consumption.

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P.17 Smoke Reduction Methods Using Shallow-Dish Combustion Chamber in an HSDI Common-Rail Diesel Engine
   

Yoshihiro Hotta, Kiyomi Nakakita,
Takayuki Fuyuto, Minaji Inayoshi

 

 

The cause of exhaust smoke from a small DI Diesel engine having small-orifice-diameter nozzles and a common-rail F.I.E. under the high-speed and high-load condition was investigated. In addition, methods by which to reduce this exhaust smoke were explored. Exhaust emission tests, in-cylinder observations and three-dimensional numerical analyses were performed. The following points were clarified during this study.

Under the abovementioned conditions, fuel sprays are easily conveyed to the squish area by a strong reverse squish. Therefore, the air in the piston cavity is not used effectively. Suppressing the airflow in the piston cavity by using a shallow-dish type combustion chamber decreases the excessive outflow of the fuel-air mixture into the squish area and allows full use of the air in the piston cavity. Hence, the exhaust smoke is reduced. This results in increased specific power, which is limited by the amount of exhaust smoke.

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P.25 NOx Selective Catalytic Reduction over Pt SupportedCatalyst Promoted by Zeolite and CeO2-ZrO2
   

Toshitaka Tanabe, Miho Hatanaka,
Ryusuke Tsuji, Hirofumi Shinjoh

 

 

The emission control of NOx in exhaust gases is one of the greatest engineering challenges to extend the practical and commercial application of diesel and lean burn engines. One solution is selective NOx reduction using hydrocarbons in an oxidizing atmosphere. We mainly focused on catalytic reactions under temperature excursion because of the resemblance to conditions prevailing in real automotive exhaust. Adsorbed hydrocarbon on zeolite was found to be highly effective in reducing NOx at elevating temperature. Thus, we proposed a novel catalyst formulation involving zeolite and CeO2-ZrO2. Our catalyst concept consists of supported Pt on thermally stable oxides (such as SiO2), zeolite and CeO2-ZrO2. Hydrocarbons adsorb on zeolite at low temperatures and migrate to the Pt surface at elevating temperature to reduce NOx. The active oxygen generated from CeO2-ZrO2 suppresses the poisoning effect of hydrocarbons at low temperature, promoting NOx reduction.

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P.32 Numerical Optimization of HC Supply for HC-DeNOx System (1) Numerical Modeling of HC-DeNOx Catalyst
   

Yoshihide Watanabe

 

 

A one-dimensional model was used to describe the transient heat and mass transfer as well as the hydrocarbon (HC) adsorption-desorption and the heterogeneous reactions of NOx and HC in diesel engine exhaust. The behavior of HC and NOx reactions and the HC adsorption-desorption in diesel exhaust have been simulated successfully under 10-15 driving cycles. A model for DeNOx catalytic reaction which takes into consideration HC adsorption and desorption and is capable of predicting the performance of DeNOx catalyst using diesel fuel as a supplemental reductant has been successfully developed.

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P.40 Numerical Optimization of HC Supply for HC-DeNOx System (2) Optimization of HC Supply Control
   

Matsuei Ueda

 

 

A new method that optimizes the control map of hydrocarbon addition to the diesel exhaust gas for hydrocarbon selective catalyst reduction has been developed. This method is comprised of a numerical HC-DeNOx catalyst model and a new optimization technique using Evolutionary Programming based on the evolution of living organisms. The numerical HC-DeNOx catalyst model was also used to describe HC adsorption-desorption.1) As a result of this evaluation, the number of calculations to obtain the optimal control map with this method was less by one third than that of all maps surveys. By using the obtained optimal control map, the NOx conversion under the Japanese 10-15 mode of the inlet-side heavily Platinum-loaded catalyst was higher by 13% than that of the uniformly Platinum-loaded catalyst in spite of the same amount of the loaded platinum. This was because the heavily platinum-loaded catalyst could start the NOx reduction at a lower temperature, enabling the optimal control map to keep the catalyst temperature within the temperature window of the catalyst for a longer time.

1) Watanabe, Y., et al. : "Development of a Model for the Lean NOx Catalytic Reaction with Hydrocarbon Adsorption and Desorption", Appl. Catal. B, Environm., 31-3(2001) 221-228

 

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P.46 Effect of Hydrocarbon Molecular Structure on Diesel Exhaust Emissions
   

Kazuhiro Akihama, Yoshiki Takatori,
Kiyomi Nakakita

 

 

In order to determine diesel fuel characteristics that might influence particulate matter (PM) emission, we have conducted a detailed investigation that combines combustion/exhaust emission measurements, in-cylinder observations, fuel analyses and chemical reactor experiments. A comparison between three representative diesel fuels, viz., "Base" (Japanese market fuel), メImprovedモ(lighter fuel with lower aromatics) and Swedish メClass-1モ yielded the following results: (1) The amount of PM emission decreases in the order of "Base" > "Class-1" > "Improved". Unexpectedly enough, "Class-1" produces more PM than "Improved" despite its significantly lower distillation temperature, and lower aromatics and sulfur content. (2) There is little difference in the combustion characteristics of the three fuels. (3) Only "Class-1" contains significant quantities of iso and naphthenic structures. (4) Flow reactor pyrolysis shows that "Class-1" produces the largest amount of PM precursors, such as benzene and toluene. These results suggest that the presence of branched and ring structures can increase exhaust PM emissions. This finding was confirmed by flow-reactor and shock tube experiments using hexanes, which revealed that iso- and cyclo-paraffins produce more benzene and soot than n-paraffins do. The results obtained in this study indicate that the specific molecular structure of the paraffinic components needs to be considered as one of the diesel fuel properties closely related to PM formation.

 

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